Role of free volume in polymer solution thermodynamics
نویسندگان
چکیده
منابع مشابه
Role of Free Volume in Polymer Solution Thermodynamics
The principal effects determining the value of the free energy of mixing of polymer solutions are discussed and compared, namely the combinatorial, energetic and structural effects. The influence of the last on the thermodynamic behaviour of polymer solutions is then dealt with, as revealed in the lower critical solution temperature. and in the effect of pressure on polymer—solvent compatibilit...
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15 صفحه اولThermodynamics of Polymer Solutions
Most of the synthetic compounds are prepared and processed in the liquid state, i.e. in solution or in the molten state. Detailed knowledge on this state is therefore indispensable. In particular it is essential to know the limits of complete miscibility with a low molecular weight solvent as a function of temperature, pressure and composition. Furthermore it is often mandatory to be acquainted...
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ژورنال
عنوان ژورنال: Pure and Applied Chemistry
سال: 1972
ISSN: 1365-3075,0033-4545
DOI: 10.1351/pac197231010133